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This review presents recent developments in the field of the highly branched molecules (excluding dendrimers) with emphasis on their surface behavior, microstructure, surface morphology, and properties. In our consideration, we included popular types of highly branched molecules, such as star molecules with multiple arms, brush macromolecules of different kinds, and hyperbranched molecules, many of...
A series of amphiphilic hyperbranched polymers with a polyester–polyol core and 64 terminal hydroxyl groups were modified by substituting various terminal groups: alkyl tails, amino, and carboxyl groups. The effect of the pendant groups' chemical composition on the resulting surface morphology within Langmuir–Blodgett monolayers with respect to their ability to form nanofibrillar surface structures...
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