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Peroxynitrite, a reactive cytotoxic species generated by the reaction of superoxide with nitric oxide, rapidly oxidizes phenylaminoethyl selenide (PAESe) and its para-substituted derivatives with second-order rate constants ranging from 900 to 3000 M -1 s -1 at neutral pH (pH 7.0) and 25 o C. These values are approximately 3 x 10 4 times greater than the corresponding...
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