The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
The cyclic alkyl(amino) carbene‐anchored silylene–phosphinidene was isolated as L−Si−P(:cAAC−Me) (L=benzamidinate) at room temperature, synthesized from the reduction of L−Si(Cl2)−P(:cAAC−Me) (1) using two equivalents of KC8. Compound 1 was prepared by the oxidative addition of a chlorophosphinidene to the benzamidinate substituted silylene center. This is the first molecular example of a silylene–phosphinidene...
Das neuartige neutrale Radikal (Me2‐cAAC)2AlCl2 (2) wird durch cyclische Alkylaminocarbene (cAACs) stabilisiert. Die Synthese erfolgte in Gegenwart eines weiteren Äquivalents Me2‐cAAC durch Reduktion des Addukts Me2‐cAAC:AlCl3 (1) mit KC8. Anhand der Kristallstruktur zeigt sich, dass die beiden Carbene, die an das Aluminiumatom gebunden sind, deutlich unterschiedliche Al‐C‐Bindungen aufweisen. Dies...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.