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In this paper, results concerning the development of sulfur tolerant catalysts for Fischer-Tropsch synthesis (FTS), C 2+ alcohol synthesis, methanol and/or DME synthesis are presented. In the FTS reaction on Fe using H 2 -rich syngas such as the biomass-derived syngas, the composition of catalyst pretreatment gas and the addition of MnO on Fe had strong impacts on its sulfur resistance...
The adsorption properties of the precipitated Co and CoMn catalysts with different ratios of cobalt to manganese reduced by H 2 were studied by in situ diffuse reflectance FTIR using CO and CO+H 2 (syngas) as probe molecules. The adsorption measurements were performed by flowing the probe gases over the samples at a high pressure of 1.2MPa. It has been found that metallic cobalt particles...
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