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l‐galactono‐1,4‐lactone dehydrogenase (GALDH) catalyzes the terminal step of vitamin C biosynthesis in plant mitochondria. Here we investigated the communication between Arabidopsis thaliana GALDH and its natural electron acceptor cytochrome c (Cc). Using laser‐generated radicals we observed the formation and stabilization of the GALDH semiquinone anionic species (GALDHSQ). GALDHSQ oxidation by Cc...
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