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Stationary and time‐resolved electron spin resonance spectroscopy measurements are employed to investigate the kinetics of the surface‐initiated reversible addition fragmentation chain transfer (RAFT) polymerization of n‐butyl acrylate from silica nanoparticles using both R‐ and Z‐group‐attached trithiocarbonates as RAFT agents. The obtained kinetic parameters reveal that the addition rate coefficient...