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Tartary buckwheat bran (TBB), which is rich in proteins, is the main waste of tartary buckwheat processing. To improve the value of TBB, the noncovalent and covalent Tartary buckwheat bran protein (TBBP)/rutin complexes were prepared, and their capacities to fabricate β‐carotene nanoemulsions were compared. The results indicated that the covalent complex exhibited the highest emulsifying performance,...