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New 3,4,5‐trisubstituted sulfamidites were prepared through cyclization of β‐amino alcohol diesters with thionyl chloride. The oxidation of these N‐alkylated sulfamidites into the corresponding sulfamidates was then performed. Interestingly, the NMR spectra of the prepared sulfamidites revealed that the ratios of the exo and endo diastereomers of these compounds were influenced by the substituents...
New erythro-β-chloroamines were synthesized by a mild and efficient stereoselective chlorination of unprotected amino alcohol diesters. These products are shown to be excellent building blocks for the synthesis of new substituted trans-oxazolidin-2-ones.
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