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A series of platinum(II) complexes bearing N‐heterocyclic carbene NHC of the type [(NHC)PtX(L)] where L is a dithiocarbamate ligand and X iodide were prepared and fully characterized. The molecular structure of one derivative was determined by single‐crystal X‐ray analyses confirming that the dithiocarbamate is acting as a bidentate ligand to the metal. All complexes demonstrated potent in vitro antiproliferative...