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A well‐defined macrocyclic aryl–CuIII complex (2) reacts readily with a variety of oxygen nucleophiles, including carboxylic acids, phenols and alcohols, under mild conditions to form the corresponding aryl esters, biaryl ethers and alkyl aryl ethers. The relationship between these reactions and catalytic CO coupling methods is demonstrated by the reaction of the macrocyclic aryl–Br species with...
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