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The self‐healing material under investigation is a diglycidyl ether of bisphenol A (DGEBA) epoxy matrix, which incorporates microcapsules filled with amine‐functionalized polydimethylsiloxane (PDMS‐a), as a new healing agent, combined with microcapsules filled with triethylenetetramine (TETA). The fracture toughness (KIC) and healing efficiency of these systems were measured using tapered double‐cantilever...