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Achieving the desired thermomechanical properties for highly solution‐processable organic semiconductors is challenging but crucial for heat tolerance of emerging optoelectronic devices. To this end, the successful synthesis of triphenylene–ethylenedioxythiophene‐dimethoxytriphenylamine (TP–ETPA), a star‐shaped organic semiconductor, is reported through a direct arylation reaction that involves ETPA,...
Organic–inorganic hybrid perovskites in high‐efficiency solar cells are prone to degradation at elevated temperatures, especially in the presence of water moisture. A hole‐transporting conjugated copolymer (abbreviated as p‐NP‐E) characteristic of alternating N‐annulated perylene and 3,4‐ethylenedioxythiophene backbones, to achieve thermostable perovskite solar cells (PSCs) via controlling gas permeation...
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