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Electrocatalytic 5‐hydroxymethylfurfural oxidation reaction (HMFOR) can replace the kinetically slow oxygen evolution reaction to yield high value‐added chemicals. In this study, interface engineering is constructed by modifying CeO2 nanoparticles on Co3O4 nanowires supported by nickel foam (NF). The construction of the heterointerface can facilitate the structural evolution of catalysts and charge...