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Photocatalysis directed at the removal of persistent organic pollutants, including pharmaceuticals, has been the subject of intense recent research. Bismuth oxychloride (BiOCl) has emerged as a potential alternative to traditional photocatalysts and has shown competitive removal efficiencies. However, pathways responsible for BiOCl photodegradation have not been well characterized. The present work...
Lanthanide-containing coordination polymers are interesting optical materials with a wide range of potential applications. In this paper we report on the detailed photophysical properties of aurophilic and nonaurophilic systems composed of Au(CN)2- and Sm(III) ions. The compounds were probed in the solid state using low-temperature luminescence spectroscopy. The luminescence lifetimes and quantum...
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