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The global adiabatic and quasidiabatic potential energy surfaces for the ground and first three excited ($$1-4\, ^3\text {A}^{\prime \prime }$$ 1-43A″ ) electronic states of $$\hbox {H}^{+} +\hbox {O}_2$$ H++O2 system are reported on a finer grid points in the Jacobi coordinates using Dunning’s cc-pVTZ basis set and internally contracted multi-reference (single and double) configuration interaction...