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Steady-state and ultrafast vibrational spectroscopy can help to elucidate the interactions between small anions and their environment because the anions’ infrared absorption frequencies and vibrational energy relaxation (VER) times depend strongly on those interactions. Their strong infrared absorptions also make many of these anions promising candidates for strong coupling to optical fields. Here,...
Solution-deposited nanoscale films of RuO2 (nanoskins) are effective transparent conductors once calcined to 200 °C. Upon heating to higher temperatures, the nanoskins show increased transmission at 550 nm, indicating changes in the optical behavior of the films. Electronic microscopy and X-ray diffraction show that the changes in the optical spectrum are accompanied by the formation of rutile RuO...
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