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Layered zinc monoglycerolate was synthesized and investigated in the methyl transesterification of soybean oil. Conversions up to 98 % were obtained at 120 °C and after the fourth cycle of use under the same conditions, the solid preserved its structure, attesting the possibility to apply this material in industrial processes. Graphical Abstract
We report the reactivity of three binuclear non-heme Fe(III) compounds, namely [Fe2(bbppnol)(μ-AcO)(H2O)2](ClO4)2 (1), [Fe2(bbppnol)(μ-AcO)2](PF6) (2), and [Fe2(bbppnol)(μ-OH)(Cl)2]·6H2O (3), where H3bbppnol = N,N′-bis(2-hydroxybenzyl)-N,N′-bis(2-methylpyridyl)–1,3-propanediamine-2-ol, toward the hydrolysis of bis-(2,4-dinitrophenyl)phosphate as models for phosphoesterase activity. The synthesis and...
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