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Copper(II) complexes of diclofenac with interesting anti-inflammatory profiles have been prepared and studied by infrared and electronic spectroscopy. In the solid state and in polar and coordinating solvents, all the complexes are solvated binuclear carboxylato-bridged complexes, [Cu(L)2(S)]2, where L is monodeprotonated diclofenac and S is the axially bonded solvent. The effect of the copper(II)...
Complexes of diclofenac (L), [CuL 2 (H 2 O)] 2 2H 2 O, and [CuL 2 (DMF)] 2 were prepared by the reaction of the sodium salt of this potent antiinflammatory drug with CuCl 2 . The new symmetric binuclear copper(II) complex [CuL 2 (DMF)] 2 crystallizes in the monoclinic space group P2 1 /n with cell constants a = 10.807(1),...
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