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Estimating the values of dispersion and biochemical reaction rates of heterogeneous aquifers is critical to predicting the temporal evolution and fate of reactive solutes. While previous studies have investigated field-scale heterogeneity of transport and biochemical properties of porous media, effects of local dispersion have not been well understood. In this paper, longitudinal macro-dispersivity,...
Over the past few decades, significant progress of assessing chemical transport in fractured rocks has been made in laboratory and field investigations as well as in mathematic modeling. In most of these studies, however, matrix diffusion on fracture–matrix surfaces is considered as a process of molecular diffusion only. Mathematical modeling based on this traditional concept often had problems in...
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