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The sulfur K-shell photoabsorption spectra (XAS) and the electron transmission spectra (ETS) have been obtained for a series of cyclic polymethylene sulfides (CH 2 ) n S with n=2,3,4,5. These spectra are dominated by similar broad resonances with trapping of the impinging (ETS) or K-shell excited (XAS) electron in σ*(S-C) and π*(CH 2 ) orbitals. Calculation of the electron...
The structures and stabilities of fluoro-substituted thiols and sulfides of general formula CH 3-n F n SH and CH 3-n F n SCH 3-n F n (n = 0-3), have been calculated at the MP2/6-311G ** and MP2/6-311 + + G ** levels. The role of F-substitution in molecules and fragments resulting from...
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