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A novel dimethyl sulfoxide/1,3-dioxolane (DMSO/1,3-DO) based electrolyte is proposed for lithium/carbon fluorides (Li/CFx) batteries to enhance the discharge voltage plateau and energy density. Conductivities of the electrolyte of 1molL−1 LiBF4/DMSO+1,3-DO with different volume ratios are not identical, which have a maximum of 14.85mScm−1. From the tests of galvanostatic discharge, the discharge voltage...