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The electrochemical behaviour of the silylene-phenylene, silylene-thienylene, silylene-diphenylene and silylene-anthranylene copolymers was investigated using cyclic voltammetry. The oxidation potentials of these organosilicon copolymers decreased with increasing dimethylsilylene chain length. The change of the oxidation potential was explained by considering the σ-π conjugation between the dimethylsilylene...