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The substructure of near-alpha Ti–Al–Sn–Zr–Mo–Si alloys containing up to 12.5at% aluminum was studied by transmission electron microscopy (TEM). It was shown that long-range order sections are formed at aging temperatures up to 500°C in alloys, high in aluminum, and the ordered phase is formed by the nucleation and growth mechanism at 700°C aging temperatures. Causes of changing the phase transformation...