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The reaction of F atoms with H 2 in an Ar matrix was studied with EPR spectroscopy. F 2 photolysis produces two well-known doublets of the H atom trapped in different crystal sites. Heating gives rise to an EPR spectrum assigned to the H 2 F complex (A H = 50.8, A F = 1.85, A H 0.15 mT), the formation of which is attributed to the reaction of diffusing...