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The osmotic and activity coefficients of aqueous magnesium chloride solutions were experimentally determined atT= 313.15 K by the isopiestic method. Lithium chloride served as the isopiestic standard for the calculation of osmotic coefficients. The molality ranges covered in this study correspond to about (0.1 to 2.5)mol · kg−1. In addition, the osmotic coefficients of aqueous mixtures of magnesium...