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A guided ion-beam tandem mass spectrometer with a flow tube ion source is used to determine the 0 K bond dissociation energy of Co + -H 2 from ligand exchange of CoCH +4 with D 2 and from collision-induced dissociation (CID) of CoH +2 + Xe. GivenD 0 (Co + -CH 4 ) = 0.93 ± 0.06 eV determined in our labs, the endothermicity of...
A guided-ion beam mass spectrometer is used to examine the collision-induced dissociation of ground state N +3 ( 3 Σ - ) from thermal to 20 eV energy with Ne, Ar, Kr, and Xe. The product distribution observed in these systems varies substantially, a result that can be attributed to the large variation in the polarizabilities and ionization energies of the rare gases....
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