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The biosynthesis of the mineralocorticoid hormone aldosterone involves a multistep hydroxylation of 11‐deoxycorticosterone at the 11‐ and 18‐positions, resulting in the formation of corticosterone and 18‐hydroxycorticosterone, the final precursor of aldosterone. Two members of the cytochrome P450 11B family, CYP11B1 and CYP11B2, are known to catalyze these 11‐ and 18‐hydroxylations, however, only...
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