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Photocatalytic hydrogen evolution is a potential route for converting inexhaustible solar energy into available clean chemical energy. Herein, highly efficient and stable Cu2(OH)2CO3/TiO2 photocatalysts for hydrogen generation are prepared by incorporating Cu2(OH)2CO3 clusters onto the surface of TiO2 through a facile precipitation method. The obtained Cu2(OH)2CO3/TiO2 photocatalyst with optimal Cu...