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The anaerobic oxidation of cysteine, Cys, by Mn(III) in acetic acid solutions has been followed by use of a stopped-flow spectrophotometric method at a temperature of 20 o C. The formation and disappearance of the [Mn(OAc) 2 Cys] - complex was monitored at 350 nm. The rate depends strongly on the acetic acid concentration (and hence also on pH) and led to the conclusion that...