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Water vapor ad/desorption isotherms were measured for a Marcellus shale at 303.15K, 313.15K and 328.15K and a relative vapor pressure up to 0.95 to investigate the adsorption behavior of water on shale. Dent’s multilayer model was applied to fit three measured adsorption isotherms simultaneously using a global fitting approach. This model can also be used to estimate the primary and secondary adsorption...
This work presents a computational study on the packing of three-dimensional carbon nanostructures and their effect on gas adsorption properties. We show that it is possible to obtain intrinsically microporous materials without specifying structural properties such as surface area or pore size distribution by packing individual graphene platelets connected at a contortion site. The resulting structures...
This work presents a combined molecular simulation and experimental study to understand the effect of graphene on the packing and gas adsorption performance of a new class of polymers, known as polymers of intrinsic microporosity (PIMs). PIMs can be processed to membranes or other useful forms and their chemistry can be tailored for specific applications. Their rigid and contorted macromolecular structures...
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