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The geometries of the 3d-transition metal-cation benzene (Bz) half-sandwich (C 6v ), M + Bz (M=Sc, Ti, V, Cr, Mn, Fe, Co, Ni, and Cu), and sandwich complexes, M + Bz 2 , in the respective staggered (D 6d ) and eclipsed (D 6h ) conformations are optimized using the B3LYP density functional in Gaussian 03. In both cases we find the respective dissociation...