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The Barclay–Butler (B-B) rule, which states that a linear relationship exists between the standard ΔH vap and ΔS vap for simple, non-associated liquids and their solutions, has been used to distinguish associated (‘abnormal’) liquids from simple (‘normal’) liquids. The exact character of the B-B plots depends on the standard states chosen for the liquid/solution and vapor. We examine...
The general nature of the problem of molecular structure in protein chemistry is discussed. As in all of organic chemistry, this problem has two aspects: the determination of the structural formula (a province of classical organic chemistry) and the determination of the molecular conformation. Recent progress in both of these areas has been great. Information on the amino acid sequences in proteins...
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