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Anhydrous calcium nitrate melts at 836 ± 2 K and subsequent decomposition occurs in the liquid phase. The temperature of NO -3 anion breakdown under dynamic rising temperature conditions increases with the heating rate, being 949 K at 10 K min -1 . Kinetic studies of this pyrolysis are reported from observations obtained by two complementary isothermal techniques. From...
A thermoanalytical study has been made of the physical and chemical changes that occur on heating equimolar mixtures of Ca(NO 3 ) 2 and sixteen selected oxides that include those of the metals of the first transition period. The work was undertaken to characterize the factors that determine the rates of thermal anion breakdown in these mixtures of initially solid reactants. It was...
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