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The electrochemical oxidation of 4-bromo-, 2,4-dibromo-, 2,4,6-tribromo- and 4-iodoanilines was investigated in acetonitrile solution. Based on the experimental results, it can be stated that the Bacon-Adams mechanism (J. Am. Chem. Soc. 90 (1968) 6596) is the main electrochemical oxidation route in acetonitrile solution similar to the 4-chloroanilines. In the cases of 4-bromo- and 2,4-dibromoanilines,...
The electrochemical oxidation of 4-chloro-, 2,4-dichloro- and 2,4,6-trichloroanilines was investigated in acetonitrile solution. Based on the experimental results, it can be stated that the mechanism introduced by J. Bacon and R.N. Adams (J. Am. Chem. Soc. 90 (1968) 6596) describing the voltammetric oxidation of 4-substituted aniline derivatives in acidic aqueous media is the main electrochemical...
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