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Mannich aminomethylation reactions involving M(aa) 2 , where M=Cu, Ni and aa=glycine(gly), dl-alanine(dl-ala), l-alanine(l-ala), with formaldehyde and diethylmalonate have been carried out, resulting in carboxylate appended systems in high yield. All the compounds have been characterized by UV-Vis spectroscopy, infrared spectroscopy and elemental analysis. One of the synthesized complexes,...
Mannich aminomethylation products have been prepared from one-pot template condensation of bis(glycinato)metal(II) complexes, M(gly) 2 , with formaldehyde and nitromethane. The synthesized compounds were characterized by suitable spectroscopic and analytical methods such as UV–Vis, infrared spectroscopy, elemental analysis, FAB mass, ESR, cyclic voltammetry, TGA and NMR. One of the synthesized...
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