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Triazinyl‐N‐oxy free radicals, 2‐methyl‐2,4,6‐triphenyl‐1,2‐dihydro‐1,3,5‐triazinyl‐1‐oxy (6 a), 2,2,4,6‐tetraphenyl‐1,2‐dihydro‐1,3,5‐triazinyl‐1‐oxy (6 b), 2,2‐dimethyl‐4,6‐diphenyl‐1,2‐dihydro‐1,3,5‐triazinyl‐1‐oxy (13), and 2,6‐dimethyl‐2,4‐diphenyl‐1,2‐dihydro‐1,3,5‐triazinyl‐1‐oxy (14), in which the unpaired electron is delocalized over three nitrogen atoms, have been prepared and characterized...
The aggregation of four charged C 60 derivatives has been investigated by TEM, SEM, and AFM microscopies. In all molecules a short aliphatic chain connects an ammonium cation to the fullerene sphere and the variation comes in the counter anions. In water, remarkably well-ordered structures that resemble nanorod-like aggregates are formed. They have a cross-sectional diameter and a length in...
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