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A highly sensitive tris(2,2′-bipyridyl)ruthenium(II) [Ru(bpy)32+] electrogenerated chemiluminescence (ECL) biosensor for the detection of ethanol based on ADH and NAD+ cofactor with ionic liquid (IL) doped sol-gel titania-Nafion composite film has been developed. Regardless of the type of the ILs, the incorporation of IL in the composite resulted in the enhancement in both the electron transfer and...