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We have analyzed chronoamperometric curves, I(t), after small-amplitude potential steps ΔE (PITT technique) for the model of linear diffusion of a species inside an electroactive film, taking into account ohmic effects in the external media (solution and electrode) as well as a finite rate of the interfacial exchange. For its short-time interval, t τ d (τ d is the diffusion time constant,...
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