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316L samples were implanted with xenon ions in order to generate defects (characterised as cavities) in the alloy subsurface region. Their oxidation kinetics in pressurized water reactor primary water at 325°C were determined using ion beam analyses. After a 24h exposure, the internal oxide layer reaches a thickness equivalent to the implanted affected depth (90nm) which does not change much for longer...
Samples of 316L were exposed at 325°C to PWR primary water labelled with deuterium and oxygen 18. The SIMS and GD-OES analysis has revealed the presence of deuterium in the internal oxide layer and in the underlying alloy. Two-stage corrosion experiments have shown that the oxygen and hydrogen transport in the oxide layer is not coupled and that the short-circuit diffusion coefficient of 18 ...
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