The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
The interaction of the chiral modifier cinchonidine with Pt(111) both in ultrahigh vacuum (UHV) and in ethanol solvent has been studied using molecular dynamics (MD) simulation. In UHV at low coverage (0.0125 molecules/Pt atom) and 298.15 K the cinchonidine was found to adsorb with the quinoline ring oriented largely parallel (α=6 o ) to the surface. Cinchonidine surface attachment was found...
The vibrational properties of adsorbed cinchonidine on polycrystalline platinum in ethanol solutions have been probed in-situ using surface-enhanced Raman spectroscopy (SERS). Analysis of the SER spectra indicates that the modifier is adsorbed through the quinoline portion of cinchonidine by π-bonding with the Pt surface. Consideration of surface selection rules suggests that the cinchonidine is at...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.