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Substituting Mn with small amounts of Co in Mn2Sb leads to kinetic arrest and magnetic frustration effects. By adding small amounts of In in place of Sb, the tetragonality and thereby the kinetic arrest properties can be modified and controlled. We investigate the kinetic arrest effect in Mn1.82Co0.18Sb1−xInx with x = 0 and 0.5 at the first-order antiferromagnetic-ferrimagnetic magnetostructural transition...
Mn2−xCrxSb exhibits an antiferromagnetic-ferrimagnetic transition of which the temperature can be adjusted by the Cr concentration. The transition temperature is at room temperature for x = 0.13, but an additional ferromagnetic MnSb impurity phase is usually inevitable at this concentration. To suppress the occurrence of this phase unfavorable for the magnetocaloric effect, we partially replace Sb...
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