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We report the crystal structure of the copper‐containing nitrite reductase (NirK) from the Gram‐negative bacterium Sinorhizobium meliloti 2011 (Sm), together with complex structural alignment and docking studies with both non‐cognate and the physiologically related pseudoazurins, SmPaz1 and SmPaz2, respectively. S. meliloti is a rhizobacterium used for the formulation of Medicago sativa bionoculants,...
We report magnetic susceptibility measurements in polycrystalline samples and EPR measurements at X-band in single crystal samples of the ternary complex of copper with aspartic acid and bipyridine, aqua(l-aspartato)(2,2 -bipyridine)copper(II) trihydrate, Cu(asp)bpy. This compound exhibits a layered structure for the copper ions. Within each layer, these ions are connected by a chemical path that...
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