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Zero Length Column chromatography was used to study mass transfer in zeolites involving coupled diffusion and immobilization mechanisms. A modeling based on Volterra integral equation technique was utilized to simulate sorption and desorption kinetic curves and compare results of the simulations with experimentally obtained curves. This approach was applied to analyze sorption kinetics in the model...
Adsorption equilibrium and kinetic data were measured for benzene on microporous gallosilicate with MFI structure (MFI-ZAG, zeolite analogous gallosilicate). The equilibrium data were found to be in general agreement with those for benzene on Ga-free MFI structures. The non-equilibrium data, as measured at elevated temperature, obey an intracrystalline molecular transport mechanism which is described...
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