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In this paper, corrosion inhibition by chemisorbed CO, at high pressure and temperature, on a high-Ni ferrous alloy (Incoloy 825) and two high-Fe alloys (13Cr-L80 (Uniloy-420) and N80 steels) in very aggressive conditions (15% (w/w) HCl solution) is described. CO was either directly dosed into the electrolyte, or produced by dehydration of formic acid. It is shown that CO is a very good corrosion...
We have carried out an electrolyte electroreflectance (EER) study of the adsorption of CO on polycrystalline Ag and Au electrodes. EER proved to be a very sensitive tool for detecting the presence of chemisorbed CO on the surface of the Ag electrode, clearly distinguishing between strong adsorption (chemisorption) and weak adsorption (physisorption). In the case of Au, onto which CO chemisorbs in...
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