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Molecular Dynamics (MD) simulations have been carried out to study the liquid–vapor phase equilibrium for the ionic liquid 1-Butyl-3-Methylimidazolium Hexafluorophosphate [C 4 mim][PF 6 ] or [bmim][PF 6 ]. The coexisting vapor–liquid densities and the critical temperature were calculated in the range of 900K–1250K. From the MD snapshots we visualized the liquid–vapor interface...