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Reactions between [Ir(COD)(PMe 3 ) 3 ]Cl, 1, and the heteroaromatic compounds thiophene, selenophene and thiazole (and substituted thiazoles) are reported. Compound 1 acts as a convenient source of the very electron-rich “Ir(PMe 3 ) 3 Cl” which is very active for oxidative addition reactions. All of the heteroaromatic compounds mentioned add via C–S or C–Se oxidative...
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