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The IR spectra of polycrystalline Mg(OH) 2 and Mg(OD) 2 are reported in the 4000–40cm −1 region. Band assignments were discussed on the basis of isotopic band shifts of the fundamental vibrations by combining the results of factor group analysis for D 3d3 crystal structure with the Teller–Redlich product rule for crystal vibrations. The band assignments proposed...