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The design, synthesis and energy transfer efficiency of a new covalently linked molecular dyad 5, which consists of 2,3-dihydrophthalazine-1,4-dione and BODIPY scaffolds, are reported. It is noteworthy that dyad 5 can induce chemiluminescence upon treatment with alkaline H2O2 in the presence of Fe(III) ions. This reaction triggers chemiluminescence resonance energy transfer (CRET) from 2,3-dihydrophthalazine-1,4-dione...
The synthesis, optical, and ion-sensing characteristics of a novel compound, 1, which is based on a 2,5-di(thien-2-yl)pyrrole scaffold with a 15-crown-5 unit, are reported. It is noteworthy that 1 can be utilized for turn-off fluorimetric detection of Pb(II) ions. The fluorescence response is based on cation-mediated reductive photoinduced electron transfer.
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