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We have investigated the adsorption and thermal decomposition of copper hexafluoroacetylacetonate (Cu II (hfac) 2 ) on single crystal rutile TiO 2 (110). Low energy electron diffraction shows that room temperature saturation coverage of the Cu II (hfac) 2 adsorbate forms an ordered (2×1) over-layer. X-ray and ultra-violet photoemission spectroscopy of the saturated...