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Miscibility, thermal, mechanical, gas permeation, morphological and surface properties of poly(vinyl chloride) (PVC) blends containing 1-10% triblock polycaprolactone-poly(dimethylsiloxane)-polycaprolactone (PCL-PDMS-PCL) copolymer were investigated by using several techniques. Fourier transform infra-red analysis of blends reveal the existence of specific interactions via hydrogen bonding between...
A new macromonomeric initiator (macroinimer) was synthesized and evaluated for the bulk polymerization of styrene at 60 and 80°C. The macroinimer containing poly(dimethylsiloxane), PDMS, was synthesized via condensation reactions between 4,-4′-azobis-4-cyanopentanoyl chloride (ACPC), PDMS and methacryloyl chloride. The product (MIM I) was thermally homopolymerized and copolymerized with styrene in...
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